<?php
$order = ($_GET['order'] == 'asc') ? 'asc' : 'desc';
$sql = "SELECT .... FROM ... WHERE ... ORDER BY TITLE $order";
mysql_query($sql) or die(mysql_error());
...
$new_order = ($order == 'asc' ) ? 'desc' : 'asc';
?>
<table>
<thead><tr>
<th><a href="scriptname.php?order=<?php echo $new_order ?>">TITLE</a></th>
<th>Total</th>
</tr></thead>
etc....